Kylian Mbappe saw his penalty saved as Liverpool beat Real Madrid 2-0 on Wednesday to inflict a third Champions League defeat in five matches on the holders.
Alexis Mac Allister and Cody Gakpo scored the goals in the second half as the Reds maintained their perfect record to return to the top of the table.
Mohamed Salah also fired wide from the spot, but it mattered little as Liverpool secured a 17th win in Arne Slot's first 19 games in charge.
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